
By
reconnecting a few tubing lines, the TOGA GC
can be used to create dissolved gas standards. A Tedlar
bag (or other container) filled with gas standard is connected
to the standard pump. The standards preparation vessel is
filled with sample liquid. The standard pump bubbles gas
standard through the standards preparation vessel, equilibrating
the liquid over time to a known concentration.

Concentration by Weight:
Hydrogen 10.7ppb
Oxygen 25.74ppm
Nitrogen 76.65ppm
Methane 70.6ppb
Carbon monoxide 207.4ppb
Carbon dioxide 518ppb
Ethylene 120.9ppb
Ethane 120.7ppb
Acetylene 86.7ppb
To
achieve these chromatograms, a transformer oil standard
was pumped through the gas extraction loop of a TOGA GC
equipped with HID and TCD detectors. The TCD was used to
quantify the oxygen and nitrogen because the HID is too
sensitive for the large quantities typically found dissolved
in transformer oil.